There's really only one move: P(not A) = 1 − P(A). The whole is always 1, so peel the event off and what's left is its complement.
The One Rule
Take the chance you know away from 1. If you know the chance an event happens, the chance it doesn't is just 1 minus that. Written tidily: P(not A) = 1 − P(A). That's the whole method — there's no step two.
A Worked One
A spinner lands on brass with probability 3/8. What's the chance it doesn't? Write the rule, drop the number in, subtract: P(not brass) = 1 − 3/8 = 8/8 − 3/8 = 5/8. Notice the little trick — to subtract a fraction from 1, write 1 as 8/8 (the same denominator), then it's an easy take-away on the top.
Fractions, Decimals or Percentages
The rule works in any costume. As a decimal: 1 − 0.375 = 0.625. As a percentage: 100% − 37.5% = 62.5%. Same chance, three outfits — the toy accepts whichever you fancy, so pick the one that matches how the question was asked.